The pitch frequency measures and describes what a beat sounds like, i.e. does the isochronic beat have a deeper bass sound, or is it high pitched and sharper sounding? The beat waveform frequency describes how many times the beat is repeating per second, i.e. how fast it is beating. You don’t really need to concern yourself about the pitch frequency, as that doesn’t have a direct influence on brainwave entrainment and doesn’t play a part on the measurement on an EEG. I only mentioned it because you were referring to humans not being able to hear below 20Hz. I change the pitch frequency just to suit the mood of the track. For tracks that are to be relaxing, for meditation or sleep, I tend to use a lower pitch frequency so it sounds deeper and more relaxing and I never have that lower than 100Hz. For an energizing, high focus track I might use a more higher pitched 200Hz isochronic tone, because that is sharper sounding and less likely to make you feel sleepy. That’s all you really need to know about the pitch frequency.
Let’s say you’re listening to a sound in your left ear that’s at a frequency of 132 Hertz (Hz). And in your right ear, you’re listening to a sound that’s at a frequency of 121 Hz. Your brain, however, gradually falls into synchrony with the difference — or 11 Hz. Instead of hearing two different tones, you instead hear a tone at 11 Hz (in addition to the two tones given to each ear).
Transparent Corp's Research Area is arguably the most comprehensive resource for collated brainwave entrainment research.   Update: the main research area on Transparent Corp's website is currently being updated, so it is offline.  However, you can still access their peer-reviewed research paper as a PDF here: “A Comprehensive Review of the Psychological Effects of Brainwave Entrainment“.
Participants were experienced practitioners of Acem Meditation, a nondirective method developed in Norway. They were asked to rest, eyes closed, for 20 minutes, and to meditate for another 20 minutes, in random order. The abundance and location of slow to fast electrical brain waves (delta, theta, alpha, beta) provide a good indication of brain activity.

Hello my name is Arvinder I really hope and pray u can help me I am really struggling I am 46 had serious insomnia aafter glandular fever at 23 since then been on all sorts of meds in the world for sleep five years back I did hypnosis while on the meds I felt really messed up and struggled to live I was on antipsychotic and sleep meds I tried to correct that mess and many many hypnosis sessions then I ended up on internet and listened to a deep sleep binaural beat music almost three years ago firer to

Slightly higher-frequency entrainment can lead to hyper suggestive states of consciousness. Still higher-frequency EEG states are associated with alert and focused mental activity needed for the optimal performance of many tasks. Perceived reality changes depending on the state of consciousness of the perceiver (Tart, 1975). Some states of consciousness provide limited views of reality, while others provide an expanded awareness of reality. For the most part, states of consciousness change in response to the ever-changing internal environment and surrounding stimulation. For example, states of consciousness are subject to influences like drugs and circadian and ultradian rhythms (Rossi, 1986; Shannahoff-Khalsa, 1991; Webb & Dube, 1981). Specific states of consciousness can also be learned as adaptive behaviors to demanding circumstances (Green and Green, 1986).  
Generally speaking, the brain will usually entrain to the strongest stimulus which would be isochronic tones over binaural beats. So when you see people add binaural beats at a different frequency to the isochronic tones, that would not produce additional brainwave entrainment at another frequency. If they are both at the same frequency I haven’t seen any research to indicate whether that would be beneficial or not, but my belief is that it would weaken the potential for entrainment. When you look at the waveform of an isochronic tone there is a distinct empty space between each beat, making it very pronounced and effective. When you add binaural beats at the same frequency it looks like this: The depth of the waveform is now half as deep and less effective. This is before the binaural beats are formed inside your head, where the waveform is hard to determine and measure. From listening to that type of combination the beats sound much less pronounced, which has to make them much less effective in terms of a brainwave entrainment stimulus, compared to isochronic tones on their own.
A few months ago I decided to test the ability of the “Equisync II” brainwaves therapy combined with other more traditional self-improvement programs and the results have been even more amazing to me. Currently in my mind I honestly believe this type of therapy can be a breakthrough, or simply the genesis of a new type of therapeutic techniques to correct several psychological, and behavioral human issues including depression, lack of organization, and self-esteem among many, many other possibilities.
This is something which will come to you with practice. For instance you may feel an energy around and inside you like you have shifted dimensions but are still there. Instead of thinking this is God, the Zone or whatever, think of this as your soul, you essence, your expanded pure light being. In this way you will begin to train yourself to find your identity in your expanded being and your internal identity. This is what we want - to let go of the idea that we are a limited ego.

a concise P.S. I was in a horrible car accident when I was 18 and had to learn to read and write and walk and talk all over again. It was long ago and I’m pretty well over it, but such an injury has lifetime repercussions. The neurological damage sustained causes my left arm to shake uncontrollably anytime I use it in a situation requiring precise coordination. From simply listening to the demo, the shake [though not disappearing completely in the last 2 months] has lessened dramatically. I had been wondering for years what kind of neurological exercises I could undergo to help it…
The use of brainwave entrainment techniques offers many benefits for overall health and well-being, including improved emotional stability, increased cognitive function, and a deepening of creative insight. Much of this benefit derives from the hemispheric synchronization occurring as a result of entrained brainwaves. This effect happens when the electrical impulses in both hemispheres synchronized to the same frequency being delivered through the entrainment source.

A binaureal beat is created by playing a different tone in each ear, and the interference pattern between the slightly differing frequencies creates the illusion of a beat. It's intended to be heard through headphones, so there's no cross-channel bleed across both ears. Listen to this, I'll play a simple binaural beat, and I'll slide the pan control back and forth from one ear to the other. You can see that there isn't actually any beat, it's just an acoustic illusion: